214000
Sigma-Aldrich

TEMPO, FREE RADICAL, 98%

Empform:

C9H18NO

Synonyms English:

2,2,6,6-Tetramethylpiperidine 1-oxyl; 2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical; TEMPO

Mdl No: MFCD00009599
Fw: 156.25
Pubchem Substance Id: 24852819
Grouped product items
SKU Pack Size Availability Price Quantity
214000-25G - Available to ship on December 30, 2023
IDR 3,014,000.00
214000-1G - Available to ship on December 30, 2023
IDR 566,000.00
214000-5G - Available to ship on December 30, 2023
IDR 946,000.00
Request a Bulk Order Check Availability

Properties

Properties
Description TEMPO, FREE RADICAL, 98%
MDM Code 214000-25G
Material Number 214000
Business Unit 774
Shipping Mode AIR
MRP Type YP
Local HS Code 29333990
Legacy SIGMA
Plant 6311
Sales Org 6304

Description

Application

TEMPO can be used:
  • As a catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.
  • As a catalytic oxidant in the iodobenzene diacetae oxidation of nerol to neral.
  • For trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene.
  • In the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.

Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air

General description

Copper/TEMPO has been utilized in the catalytic oxidation of primary alcohols to aldehydes.

SAFETY INFORMATION

Signal Word

Danger

P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

RIDADRRIDADR

WGK Germany

WGK 3

Flash Point (F)

152.6 °F - closed cup

Flash Point (C)

67 °C - closed cup

Target Organs

Risk Statement

Supplemental Hazard Statements

DOCUMENTATION

Certificate of Analysis View Sample COA
Certificate of Origin

TECHNICAL SERVICE

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