[3:39 PM] Rifki Akbar

Hazard and Precautionary Statements

  • Hazard Statements
  • Precautionary Statements
  • Pictograms and Hazard Codes

  • HAZARD STATEMENTS

    There are 72 individual and 17 combined Hazard statements - these are assigned a unique alphanumerical code which consists of one letter and three numbers as follows:

    • the letter "H" (for "hazard statement");
    • a number designating the type of hazard as follows:
      • "2" for physical hazards
      • "3" for health hazards
      • "4" for environmental hazards
    • two numbers corresponding to the sequential numbering of hazards arising from the intrinsic properties of the substance or mixture, such as explosive properties (codes from 200 to 210), flammability (codes from 220 to 230), etc.

    Hazard Statement Overview

      Code Hazard statements Hazard class Category Signal word P-Codes
      H200 Unstable Explosive Explosives Unstable Explosive Danger P201, P202, P281, P372, P373, P380, P401, P501
      H201 Explosive;
      mass explosion hazard
      Explosives Div 1.1 Danger P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501
      H202 Explosive;
      severe projection hazard
      Explosives Div 1.2 Danger P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501
      H203 Explosive; fire,
      blast or projection hazard
      Explosives Div 1.3 Danger P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501
      H204 Fire or
      projection hazard
      Explosives Div 1.4 Warning P210, P240, P250, P280, P370+P380, P372, P373, P374, P401, P501
      H205 May mass explode in fire Explosives Div 1.5
      Div 1.6
      Danger P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501
      H220 Extremely flammable gas Flammable gases Category 1 Danger P210, P377, P381, P403
      H221 Flammable gas Flammable gases Category 2 Warning P210, P377, P381, P403
      H222 Extremely flammable aerosol Flammable aerosols Category 1 Danger P210, P211, P251, P410+P412
      H223 Flammable aerosol Flammable aerosols Category 2 Warning P210, P211, P251, P410+P412
      H224 Extremely flammable
      liquid and vapour
      Flammable liquids Category 1 Danger P210,P233, P240, P241, P242, P243, P280, P303+ P361+P353, P370+P378, P403+P235, P501
      H225 Highly Flammable
      liquid and vapour
      Flammable liquids Category 2 Danger
      H226 Flammable liquid
      and vapour
      Flammable liquids Category 3 Warning
      H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235, P501
      H228 Flammable solid Flammable liquids Category 1 Danger P210, P240,P241, P280, P370+P378
      H228 Flammable solid Flammable liquids Category 2 Warning
      H240 Heating may cause an explosion Self-reactive substances
      and mixtures; and Organic peroxide
      Type A Danger P210, P220, P234, P280, P370+ P378, P370+ P380+P375, P403+P235, P411, P420, P501
      H241 Heating may cause a fire or explosion Self-reactive substances
      and mixtures;
      and Organic peroxides
      Type B Danger P210, P220, P234, P280, P370+P378, P370+ P380+P375, P403+P235, P411, P420, P501
      H242 Heating may cause a fire Self-reactive substances
      and mixtures;
      and Organic peroxides
      Type C, D Danger P210, P220, P234, P280, P370+P378, P403+P235, P411, P420, P501
      H242 Heating may cause a fire Self-reactive substances and mixtures;
      and Organic peroxides
      Type E, F
      Type G
      Warning P210, P220, P234, P280, P370+P378, P403+P235, P411, P420, P501
      H250 Catches fire spontaneously
      if exposed to air
      Pyrophoric liquids;
      Pyrorophoric solids
      Category 1 Danger P210, P222, P280, P302+P334, P370+P378, P422
      H251 Self-heating;
      may catch fire
      Self-heating substances
      and mixtures
      Category 1 Danger
      H252 Self-heating in large quantities;
      may catch fire
      Self-heating substances
      and mixtures
      Category 2 Warning P235+P410, P280, P407, P413, P420
      H260 In contact with water
      releases flammable gases
      which may ignite spontaneously
      Substances And Mixtures Which,
      In Contact With Water,
      Emit Flammable Gases
      Category 1 Danger
      H261 In contact with water
      releases flammable gas
      Substances And Mixtures Which,
      In Contact With Water,
      Emit Flammable Gases
      Category 2 Danger P223, P231+P232, P280, P335+ P334, P370+P378, P402+P404, P501
      H261 In contact with water releases flammable gas Substances And Mixtures Which,
      In Contact With Water,
      Emit Flammable Gases
      Category 3 Warning P223, P231+P232, P280, P335+ P334, P370+P378, P402+P404, P501
      H270 May cause or intensify fire;
      oxidizer
      Oxidising gases Category 1 Danger P220, P244, P370+P376, P403
      H271 May cause fire or explosion;
      strong oxidiser
      Oxidising liquids;
      Oxidising solids
      Category 1 Danger P210, P220, P221, P280, P283, P306+P360, P371+P380+P375, P370+P378, P501
      H272 May intensify fire;
      oxidizer
      Oxidising liquids;
      Oxidising solids
      Category 2 Danger
      H272 May intensify fire;
      oxidizer
      Oxidising liquids;
      Oxidising solids
      Category 3 Warning P210, P220, P221P280, P370+P378, P501
      H280 Contains gas under pressure;
      may explode if heated
      Gases under pressure Compressed gas
      Liquefied gas
      Dissolved gas
      Warning P410+P403
      H281 Contains refrigerated gas;
      may cause cryogenic burns or injury
      Gases under pressure Refrigerated liquefied gas Warning P282, P336, P315, P403
      H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
      H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330, P405, P501
      H301 Toxic if swallowed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330, P405, P501
      H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
      H303 May be harmful if swallowed Acute toxicity,oral Category 5 Warning P312
      H304 May be fatal if swallowed
      and enters airways
      Aspiration hazard Category 1 Danger
      H305 May be fatal if swallowed
      and enters airways
      Aspiration hazard Category 2 Warning P301+P310, P331, P405, P501
      H310 Fatal in contact with skin Acute toxicity,
      dermal
      Category 1, 2 Danger P262, P264, P270, P280, P302+P350, P310, P322, P361, P363, P405, P501
      H311 Toxic in contact with skin Acute toxicity,
      dermal
      Category 3 Danger P280, P302+P352, P312, P322, P361, P363, P405, P501
      H312 Harmful in contact with skin Acute toxicity,
      dermal
      Category 4 Warning P280,P302+P352, P312, P322, P363, P501
      H313 May be harmful in contact with skin Acute toxicity,
      dermal
      Category 5 Warning P312
      H314 Causes severe skin burns
      and eye damage
      Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331, P303+P361+P353, P363, P304+P340, P310, P321, P305+ P351+P338, P405, P501
      H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321, P332+P313, P362
      H316 Causes mild skin irritation Skin corrosion/irritation Category 3 Warning PP332+P313
      H317 May cause an allergic skin reaction Sensitisation,
      Skin
      Category 1 Warning P261, P272, P280, P302+P352, P333+P313, P321, P363, P501
      H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
      H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338, P337+P313P
      H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338, P337+P313
      H330 Fatal if inhaled Acute toxicity,
      inhalation
      Category 1, 2 Danger P260, P271, P284, P304+P340, P310, P320, P403+P233, P405, P501
      H331 Toxic if inhaled Acute toxicity,
      inhalation
      Category 3 Danger P261, P271, P304+P340, P311, P321, P403+P233, P405, P501
      H332 Harmful if inhaled Acute toxicity,
      inhalation
      Category 4 Warning P261, P271, P304+P340, P312
      H333 May be harmful if inhaled Acute toxicity,
      inhalation
      Category 5 P304+P312
      H334 May cause allergy
      or asthma symptoms
      or breathing difficulties if inhaled
      Sensitisation,
      respiratory
      Category 1 Danger P261, P285, P304+P341, P342+P311, P501
      H335 May cause respiratory irritation Specific target organ toxicity,
      single exposure;
      Respiratory
      tract irritation
      Category 3 Warning
      H336 May cause drowsiness
      or dizziness
      Specific target organ toxicity,
      single exposure;
      Narcotic effects
      Category 3 Warning P261, P271, P304+P340, P312, P403+P233, P405, P501
      H340 May cause genetic defects Germ cell mutagenicity Category 1A, 1B Danger
      H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405, P501
      H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
      H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405, P501
      H360 May damage fertility
      or the unborn child
      Reproductive toxicity Category 1A, 1B Danger
      H361 Suspected of damaging fertility
      or the unborn child
      Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405, P501
      H362 May cause harm to breast-fed children Reproductive toxicity,
      effects on or via lactation
      Additional category P201, P260, P263, P264, P270, P308+P313
      H370 Causes damage to organs Specific target organ toxicity,
      single exposure
      Category 1 Danger P260, P264, P270, P307+P311, P321, P405, P501
      H371 May cause damage to organs Specific target organ toxicity,
      single exposure
      Category 2 Warning P260, P264, P270, P309+P311, P405, P501
      H372 Causes damage to organs through prolonged
      or repeated exposure
      Specific target organ toxicity,
      repeated exposure
      Category 1 Danger P260, P264, P270, P314, P501
      H373 May cause damage to organs
      through prolonged
      or repeated exposure
      Specific target organ toxicity,
      repeated exposure
      Category 2 Warning P260, P314, P501
      H400 Very toxic to aquatic life Hazardous to the aquatic environment,
      acute hazard
      Category 1 Warning P273, P391, P501
      H401 Toxic to aquatic life Hazardous to the aquatic environment,
      acute hazard
      Category 2 P273, P501
      H402 Harmful to aquatic life Hazardous to the aquatic environment,
      acute hazard
      Category 3
      H410 Very toxic to aquatic life
      with long lasting effects
      Hazardous to the aquatic environment,
      long-term hazard
      Category 1 Warning P273, P391, P501
      H411 Toxic to aquatic life
      with long lasting effects
      Hazardous to the aquatic environment,
      long-term hazard
      Category 2
      H412 Harmful to aquatic life
      with long lasting effects
      Hazardous to the aquatic environment,
      long-term hazard
      Category 3
      H413 May cause long lasting
      harmful effects to aquatic life
      Hazardous to the aquatic environment,
      long-term hazard
      Category 4 P273, P501
      H420 Harms public health and
      the environment by destroying ozone in the upper atmosphere
      Hazardous to the ozone layer Category 1 Warning P502
      Additional Hazard statements - EU Left-overs
      EUH001 Explosive when dry
      EUH006 Explosive with or without contact with air
      EUH014 Reacts violently with water
      EUH018 In use may form flammable/explosive vapour-air mixture
      EUH019 May form explosive peroxides
      EUH029 Contact with water liberates toxic gas
      EUH031 Contact with acids liberates toxic gas
      EUH032 Contact with acids liberates very toxic gas
      EUH044 Risk of explosion if heated under confinement
      EUH059 Hazardous to the ozone layer
      EUH066 Repeated exposure may cause skin dryness or cracking
      EUH070 Toxic by eye contact

      PRECAUTIONARY STATEMENTS

      There are 116 individual and 33 combined Precautionary statements – these are assigned a unique alphanumerical code which consists of one letter and three numbers as follows:

      • the letter "P" (for "precautionary statement");
      • one number designating the type of precautionary statement as follows:
        • "1" for general precautionary statements
        • "3" for response precautionary statements
        • "4" for storage precautionary statements
        • "5" for disposal precautionary statements
      • two numbers (corresponding to the sequential numbering of precautionary statements)

      Precautionary Statement Overview

        General
        P101 If medical advice is needed,have product container or label at hand.
        P102 Keep out of reach of children.
        P103 Read label before use
        Prevention
        P201 Obtain special instructions before use.
        P202 Do not handle until all safety precautions have been read and understood.
        P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
        P211 Do not spray on an open flame or other ignition source.
        P220 Keep/Store away from clothing/…/combustible materials.
        P221 Take any precaution to avoid mixing with combustibles/…
        P222 Do not allow contact with air.
        P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
        P230 Keep wetted with …
        P231 Keep wetted with …
        P232 Protect from moisture.
        P233 Keep container tightly closed.
        P234 Keep only in original container.
        P235 Keep cool.
        P240 Ground/bond container and receiving equipment.
        P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
        P242 Use only non-sparking tools.
        P243 Take precautionary measures against static discharge.
        P244 Keep reduction valves free from grease and oil.
        P250 Do not subject to grinding/shock/…/friction.
        P251 Pressurized container: Do not pierce or burn, even after use.
        P260 Do not breathe dust/fume/gas/mist/vapours/spray.
        P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
        P262 Do not get in eyes, on skin, or on clothing.
        P263 Avoid contact during pregnancy/while nursing.
        P264 Wash hands thoroughly after handling.
        P270 Do not eat, drink or smoke when using this product.
        P271 Use only outdoors or in a well-ventilated area.
        P272 Contaminated work clothing should not be allowed out of the workplace.
        P273 Avoid release to the environment.
        P280 Wear protective gloves/protective clothing/eye protection/face protection.
        P281 Use personal protective equipment as required.
        P282 Wear cold insulating gloves/face shield/eye protection.
        P283 Wear fire/flame resistant/retardant clothing.
        P284 Wear respiratory protection.
        P285 In case of inadequate ventilation wear respiratory protection.
        P231 + P232 Handle under inert gas. Protect from moisture.
        P235 + P410 Keep cool. Protect from sunlight.
        Response
        P301 IF SWALLOWED:
        P304 IF INHALED:
        P305 IF IN EYES:
        P306 IF ON CLOTHING:
        P307 IF exposed:
        P308 IF exposed or concerned:
        P309 IF exposed or if you feel unwell:
        P310 Immediately call a POISON CENTER or doctor/physician.
        P311 Call a POISON CENTER or doctor/physician.
        P312 Call a POISON CENTER or doctor/physician if you feel unwell.
        P313 Get medical advice/attention.
        P314 Get medical advice/attention if you feel unwell.
        P315 Get immediate medical advice/attention.
        P320 Specific treatment is urgent (see … on this label).
        P321 Specific treatment (see … on this label).
        P322 Specific measures (see …on this label).
        P330 Rinse mouth.
        P331 Do NOT induce vomiting.
        P332 IF SKIN irritation occurs:
        P333 If skin irritation or rash occurs:
        P334 Immerse in cool water/wrap n wet bandages.
        P335 Brush off loose particles from skin.
        P336 Thaw frosted parts with lukewarm water. Do not rub affected area.
        P337 If eye irritation persists:
        P338 Remove contact lenses, if present and easy to do. Continue rinsing.
        P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
        P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position
        P342 If experiencing respiratory symptoms:
        P350 Gently wash with plenty of soap and water.
        P351 Rinse cautiously with water for several minutes.
        P352 Wash with plenty of soap and water.
        P353 Rinse skin with water/shower.
        P360 Rinse immediately contaminated clothing and skin with plenty of water before removin
        P361 Remove/Take off immediately all contaminated clothing.
        P362 Take off contaminated clothing and wash before reuse.
        P363 Wash contaminated clothing before reuse.
        P370 In case of fire:
        P371 In case of major fire and large quantities:
        P372 Explosion risk in case of fire.
        P373 DO NOT fight fire when fire reaches explosives.
        P374 Fight fire with normal precautions from a reasonable distance.
        P376 Stop leak if safe to do so. Oxidising gases (section 2.4) 1
        P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
        P378 Use … for extinction.
        P380 Evacuate area.
        P381 Eliminate all ignition sources if safe to do so.
        P390 Absorb spillage to prevent material damage.
        P391 Collect spillage. Hazardous to the aquatic environment.
        P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
        P301 + P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
        P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
        P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water.
        P302 + P352 IF ON SKIN: wash with plenty of soap and water.
        P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
        P304 + P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
        P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
        P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
        P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
        P306 + P360 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
        P307 + P311 IF exposed: call a POISON CENTER or doctor/physician.
        P308 + P313 IF exposed or concerned: Get medical advice/attention.
        P309 + P311 IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
        P332 + P313 IF SKIN irritation occurs: Get medical advice/attention.
        P333 + P313 IF SKIN irritation or rash occurs: Get medical advice/attention.
        P335 + P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
        P337 + P313 IF eye irritation persists: Get medical advice/attention.
        P342 + P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
        P370 + P376 in case of fire: Stop leak if safe to Do so.
        P370 + P378 In case of fire: Use … for extinction.
        P370 + P380 in case of fire: Evacuate area.
        P370 + P380 + P375 in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
        P371 + P380 + P375 in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

        PICTOGRAMS AND HAZARD CODES

        Compared to the current EU system the most noticeable change are the pictograms (formerly: hazard symbols). While the most of the GHS pictograms have an equivalent in the old system, the pictograms GHS 04, GHS 07 and GHS 08 are completely new.

        The GHS System is built on 16 physical, 10 health and 3 environmental hazard classes and comprises the following communication elements:


        Description Pictogram Hazard class and hazard category:
        Exploding Bomb GHS01 Exploding Bomb GHS01 Unstable explosives
        Explosives of Divisions 1.1, 1.2, 1.3, 1.4
        Self reactive substances and mixtures, Types A,B
        Organic peroxides, Types A,B
        Fire or projection hazard Division 1.5
        May mass explode in fire Division 1.6
        Flame GHS02 Flame GHS02	Flammable gases, category 1
        Flammable aerosols, categories 1,2
        Flammable liquids, categories 1,2,3
        Flammable solids, categories 1,2
        Self-reactive substances and mixtures, Types B,C,D,E,F
        Pyrophoric liquids, category 1
        Pyrophoric solids, category 1
        Self-heating substances and mixtures, categories 1,2
        Substances and mixtures, which in contact with water,
        emit flammable gases, categories 1,2,3
        Organic peroxides, Types B,C,D,E,F
        Flame Over Circle GHS03 Flame Over Circle GHS03 Oxidizing gases, category 1 Oxidizing liquids, categories 1,2,3
        Gas Cylinder GHS04 Gas Cylinder GHS04 Gases under pressure:
        Compressed gases
        Liquefied gases
        Refrigerated liquefied gases
        Dissolved gases
        Corrosion GHS05 Corrosion GHS05 Corrosive to metals, category 1
        Skin corrosion, categories 1A,1B,1C
        Serious eye damage, category 1
        Skull and Crossbones GHS06 Skull and Crossbones GHS06 Acute toxicity (oral, dermal, inhalation), categories 1,2,3
        Exclamation Mark GHS07 Exclamation Mark GHS07 Acute toxicity (oral, dermal, inhalation), category 4
        Skin irritation, category 2
        Eye irritation, category 2
        Skin sensitisation, category 1
        Specific Target Organ Toxicity – Single exposure, category 3
        Health Hazard GHS08 Health Hazard GHS08 Respiratory sensitization, category 1
        Germ cell mutagenicity, categories 1A,1B,2
        Carcinogenicity, categories 1A,1B,2
        Reproductive toxicity, categories 1A,1B,2
        Specific Target Organ Toxicity – Single exposure, categories 1,2
        Specific Target Organ Toxicity – Repeated exposure, categories 1,2
        Aspiration Hazard, category 1
        Environment GHS09 Environment GHS09 Hazardous to the aquatic environment
        - Acute hazard, category1
        - Chronic hazard, categories 1,2

        RELATED APPLICATIONS

        1. Hazard and Precautionary Statements
          <!DOCTYPE html> <html> <body> <li><a href="#hazard">Hazard Statements</a></li> <li><a href="#precautionary">Precautionary Statements</a></li> <li><a href="#pictogram">Pictograms and Hazard Codes</a></li> <br> <h2><a id="hazard"></a>HAZARD STATEMENTS</h2> <p><b>There are 72 individual and 17 combined Hazard statements</b> - these are assigned a unique alphanumerical code which consists of one letter and three numbers as follows:</p> <ul> <li>the letter &quot;H&quot; (for &quot;hazard statement&quot;);</li> <li>a number designating the type of hazard as follows: <ul> <li>&quot;2&quot; for physical hazards</li> <li>&quot;3&quot; for health hazards</li> <li>&quot;4&quot; for environmental hazards</li> </ul> </li> <li>two numbers corresponding to the sequential numbering of hazards arising from the intrinsic properties of the substance or mixture, such as explosive properties (codes from 200 to 210), flammability (codes from 220 to 230), etc. </li> </ul> <br> <style> .button2 { border: 3px solid #007CBA ; border-radius: 10px; color: white; padding: 10px 20px; text-align: center; text-decoration: none; font-size: 18px; margin: 3px 0px; cursor: pointer; } .button2 {background-color: #007CBA;} </style> <a target="_blank" href="https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/307/998/h_overview.pdf" class="button button2"> <font color="white"><strong>Hazard Statement Overview</strong></font> </a> </button> <ul> <br> <!DOCTYPE html> <html> <head> <meta name="viewport" content="width=device-width, initial-scale=1"> <style> .collapsible { background-color: #f1f1f1; color: black; cursor: pointer; padding: 18px; width: 100%; border: none; text-align: left; font-size: 18px; } .content { padding: 0 30px; max-height: 0; overflow: hidden; background-color: #f1f1f1; word-wrap: break-word; column-gap: 50px; } </style> </head> <body> <button class="collapsible"></i> &#x25BC <b>HAZARD STATEMENT CHART</b></button> <div class="content"> <style> th,td,tr { border-bottom: solid; border-bottom-color: #b6b7b8; border-bottom-width: 1px;} th{ background-color: #FFFFFF; } th, td{ word-wrap: break-word; } th, td { padding-top: 40px; padding-bottom: 40px; padding-left: 30px; padding-right: 50px; column-gap: 70px; } table { border-spacing: 00px; } th, td { text-align: left;} Td,th { font-size: 95%; } td { font-weight: normal; } table,th,td { column-gap: 50px; } </style> <table style="width:100%"> <div><th style="width:10%">Code</th> <th style="width:25%">Hazard statements</th> <th style="width:25%">Hazard class</th> <th style="width:20%">Category</th> <th style="width:15%">Signal word</th> <th style="width:30%">P-Codes</th> <tr> <td>H200</td> <td>Unstable Explosive</td> <td>Explosives</td> <td>Unstable Explosive</td> <td>Danger</td> <td>P201, P202, P281, P372, P373, P380, P401, P501</td> <tr> <td>H201</td> <td>Explosive; <br>mass explosion hazard </td> <td>Explosives</td> <td>Div 1.1 </td> <td>Danger</td> <td>P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501</td> <tr> <td>H202</td> <td>Explosive; <br>severe projection hazard </td> <td>Explosives</td> <td>Div 1.2 </td> <td>Danger</td> <td>P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501</td> <tr> <td>H203</td> <td>Explosive; fire, <br>blast or projection hazard </td> <td>Explosives</td> <td>Div 1.3 </td> <td>Danger</td> <td>P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501</td> <tr> <td>H204</td> <td>Fire or <br>projection hazard </td> <td>Explosives</td> <td>Div 1.4 </td> <td>Warning</td> <td>P210, P240, P250, P280, P370+P380, P372, P373, P374, P401, P501</td> <tr> <td>H205</td> <td>May mass explode in fire </td> <td>Explosives</td> <td>Div 1.5 <br> Div 1.6</td> <td>Danger</td> <td>P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, P501</td> <tr> <td>H220</td> <td>Extremely flammable gas</td> <td>Flammable gases </td> <td>Category 1 </td> <td>Danger</td> <td>P210, P377, P381, P403</td> <tr> <td>H221</td> <td>Flammable gas </td> <td>Flammable gases </td> <td>Category 2 </td> <td>Warning</td> <td>P210, P377, P381, P403</td> <tr> <td>H222</td> <td>Extremely flammable aerosol</td> <td>Flammable aerosols </td> <td>Category 1</td> <td>Danger</td> <td>P210, P211, P251, P410+P412</td> <tr> <td>H223</td> <td>Flammable aerosol </td> <td>Flammable aerosols </td> <td>Category 2 </td> <td>Warning</td> <td>P210, P211, P251, P410+P412</td> <tr> <td>H224</td> <td>Extremely flammable <br>liquid and vapour </td> <td>Flammable liquids </td> <td>Category 1 </td> <td>Danger</td> <td>P210,P233, P240, P241, P242, P243, P280, P303+ P361+P353, P370+P378, P403+P235, P501</td> <tr> <td>H225</td> <td>Highly Flammable <br>liquid and vapour </td> <td>Flammable liquids </td> <td>Category 2 </td> <td>Danger</td> <td></td> <tr> <td>H226</td> <td>Flammable liquid <br>and vapour </td> <td>Flammable liquids </td> <td>Category 3 </td> <td>Warning</td> <td></td> <tr> <td>H227</td> <td>Combustible liquid </td> <td>Flammable liquids </td> <td>Category 4 </td> <td>Warning</td> <td>P210, P280, P370+P378, P403+P235, P501</td> <tr> <td>H228</td> <td>Flammable solid </td> <td>Flammable liquids </td> <td>Category 1 </td> <td>Danger</td> <td>P210, P240,P241, P280, P370+P378</td> <tr> <td>H228</td> <td>Flammable solid </td> <td>Flammable liquids </td> <td>Category 2 </td> <td>Warning</td> <td></td> <tr> <td>H240</td> <td>Heating may cause an explosion </td> <td>Self-reactive substances <br> and mixtures; and Organic peroxide </td> <td>Type A </td> <td>Danger</td> <td>P210, P220, P234, P280, P370+ P378, P370+ P380+P375, P403+P235, P411, P420, P501 </td> <tr> <td>H241</td> <td>Heating may cause a fire or explosion </td> <td>Self-reactive substances <br> and mixtures; <br>and Organic peroxides</td> <td>Type B </td> <td>Danger</td> <td>P210, P220, P234, P280, P370+P378, P370+ P380+P375, P403+P235, P411, P420, P501 </td> <tr> <td>H242</td> <td>Heating may cause a fire </td> <td>Self-reactive substances <br>and mixtures; <br>and Organic peroxides</td> <td>Type C, D </td> <td>Danger</td> <td>P210, P220, P234, P280, P370+P378, P403+P235, P411, P420, P501</td> <tr> <td>H242</td> <td>Heating may cause a fire </td> <td>Self-reactive substances and mixtures; <br>and Organic peroxides</td> <td>Type E, F <br> Type G</td> <td>Warning</td> <td>P210, P220, P234, P280, P370+P378, P403+P235, P411, P420, P501</td> <tr> <td>H250</td> <td>Catches fire spontaneously <br>if exposed to air </td> <td>Pyrophoric liquids;<br> Pyrorophoric solids </td> <td>Category 1 </td> <td>Danger</td> <td>P210, P222, P280, P302+P334, P370+P378, P422</td> <tr> <td>H251</td> <td>Self-heating; <br>may catch fire </td> <td>Self-heating substances <br>and mixtures</td> <td>Category 1 </td> <td>Danger</td> <td></td> <tr> <td>H252</td> <td>Self-heating in large quantities; <br>may catch fire</td> <td>Self-heating substances <br>and mixtures</td> <td>Category 2 </td> <td>Warning</td> <td>P235+P410, P280, P407, P413, P420</td> <tr> <td>H260</td> <td>In contact with water <br>releases flammable gases <br>which may ignite spontaneously</td> <td>Substances And Mixtures Which, <br>In Contact With Water, <br>Emit Flammable Gases</td> <td>Category 1 </td> <td>Danger</td> <td></td> <tr> <td>H261</td> <td>In contact with water <br> releases flammable gas</td> <td>Substances And Mixtures Which, <br>In Contact With Water, <br>Emit Flammable Gases</td> <td>Category 2 </td> <td>Danger</td> <td>P223, P231+P232, P280, P335+ P334, P370+P378, P402+P404, P501</td> <tr> <td>H261</td> <td>In contact with water releases flammable gas</td> <td>Substances And Mixtures Which, <br>In Contact With Water, <br>Emit Flammable Gases</td> <td>Category 3 </td> <td>Warning</td> <td>P223, P231+P232, P280, P335+ P334, P370+P378, P402+P404, P501</td> <tr> <td>H270</td> <td>May cause or intensify fire; <br>oxidizer</td> <td>Oxidising gases </td> <td>Category 1 </td> <td>Danger</td> <td>P220, P244, P370+P376, P403</td> <tr> <td>H271</td> <td>May cause fire or explosion; <br>strong oxidiser </td> <td>Oxidising liquids;<br>Oxidising solids</td> <td>Category 1 </td> <td>Danger</td> <td>P210, P220, P221, P280, P283, P306+P360, P371+P380+P375, P370+P378, P501</td> <tr> <td>H272</td> <td>May intensify fire; <br>oxidizer </td> <td>Oxidising liquids;<br>Oxidising solids</td> <td>Category 2 </td> <td>Danger</td> <td></td> <tr> <td>H272</td> <td>May intensify fire; <br>oxidizer </td> <td>Oxidising liquids;<br>Oxidising solids</td> <td>Category 3 </td> <td>Warning</td> <td>P210, P220, P221P280, P370+P378, P501</td> <tr> <td>H280</td> <td>Contains gas under pressure; <br>may explode if heated </td> <td>Gases under pressure </td> <td>Compressed gas <br> Liquefied gas <br> Dissolved gas</td> <td>Warning</td> <td>P410+P403</td> <tr> <td>H281</td> <td>Contains refrigerated gas; <br>may cause cryogenic burns or injury</td> <td>Gases under pressure </td> <td>Refrigerated liquefied gas</td> <td>Warning</td> <td>P282, P336, P315, P403</td> <tr> <td>H290</td> <td>May be corrosive to metals </td> <td>Corrosive to Metals </td> <td>Category 1 </td> <td>Warning</td> <td>P234, P390, P404</td> <tr> <td>H300</td> <td>Fatal if swallowed </td> <td>Acute toxicity,oral </td> <td>Category 1, 2</td> <td>Danger</td> <td>P264, P270, P301+P310, P321, P330, P405, P501</td> <tr> <td>H301</td> <td>Toxic if swallowed </td> <td>Acute toxicity,oral </td> <td>Category 3</td> <td>Danger</td> <td>P264, P270, P301+P310, P321, P330, P405, P501</td> <tr> <td>H302</td> <td>Harmful if swallowed</td> <td>Acute toxicity,oral </td> <td>Category 4 </td> <td>Warning</td> <td>P264, P270, P301+P312, P330, P501</td> <tr> <td>H303</td> <td>May be harmful if swallowed </td> <td>Acute toxicity,oral </td> <td>Category 5 </td> <td>Warning</td> <td>P312</td> <tr> <td>H304</td> <td>May be fatal if swallowed <br> and enters airways </td> <td>Aspiration hazard </td> <td>Category 1 </td> <td>Danger</td> <td></td> <tr> <td>H305</td> <td>May be fatal if swallowed <br> and enters airways </td> <td>Aspiration hazard </td> <td>Category 2 </td> <td>Warning</td> <td>P301+P310, P331, P405, P501</td> <tr> <td>H310</td> <td>Fatal in contact with skin </td> <td>Acute toxicity,<br>dermal </td> <td>Category 1, 2 </td> <td>Danger</td> <td>P262, P264, P270, P280, P302+P350, P310, P322, P361, P363, P405, P501</td> <tr> <td>H311</td> <td>Toxic in contact with skin </td> <td>Acute toxicity,<br>dermal </td> <td>Category 3 </td> <td>Danger</td> <td>P280, P302+P352, P312, P322, P361, P363, P405, P501</td> <tr> <td>H312</td> <td>Harmful in contact with skin </td> <td>Acute toxicity,<br>dermal </td> <td>Category 4</td> <td>Warning</td> <td>P280,P302+P352, P312, P322, P363, P501</td> <tr> <td>H313</td> <td>May be harmful in contact with skin </td> <td>Acute toxicity,<br>dermal </td> <td>Category 5 </td> <td>Warning</td> <td>P312</td> <tr> <td>H314</td> <td>Causes severe skin burns <br>and eye damage </td> <td>Skin corrosion/irritation </td> <td>Category 1A, B, C </td> <td>Danger</td> <td>P260,P264, P280, P301+P330+ P331, P303+P361+P353, P363, P304+P340, P310, P321, P305+ P351+P338, P405, P501</td> <tr> <td>H315</td> <td>Causes skin irritation </td> <td>Skin corrosion/irritation </td> <td>Category 2 </td> <td>Warning</td> <td>P264, P280, P302+P352, P321, P332+P313, P362</td> <tr> <td>H316</td> <td>Causes mild skin irritation </td> <td>Skin corrosion/irritation </td> <td>Category 3 </td> <td>Warning</td> <td>PP332+P313</td> <tr> <td>H317</td> <td>May cause an allergic skin reaction </td> <td>Sensitisation,<br> Skin </td> <td>Category 1 </td> <td>Warning</td> <td>P261, P272, P280, P302+P352, P333+P313, P321, P363, P501</td> <tr> <td>H318</td> <td>Causes serious eye damage </td> <td>Serious eye damage/eye irritation </td> <td>Category 1 </td> <td>Danger</td> <td>P280, P305+P351+P338, P310</td> <tr> <td>H319</td> <td>Causes serious eye irritation </td> <td>Serious eye damage/eye irritation </td> <td>Category 2A </td> <td>Warning </td> <td>P264, P280, P305+P351+P338, P337+P313P</td> <tr> <td>H320</td> <td>Causes eye irritation </td> <td>Serious eye damage/eye irritation </td> <td>Category 2B </td> <td>Warning </td> <td>P264, P305+P351+P338, P337+P313</td> <tr> <td>H330</td> <td>Fatal if inhaled </td> <td>Acute toxicity,<br>inhalation </td> <td>Category 1, 2 </td> <td>Danger</td> <td>P260, P271, P284, P304+P340, P310, P320, P403+P233, P405, P501</td> <tr> <td>H331</td> <td>Toxic if inhaled </td> <td>Acute toxicity,<br>inhalation </td> <td>Category 3 </td> <td>Danger</td> <td>P261, P271, P304+P340, P311, P321, P403+P233, P405, P501</td> <tr> <td>H332</td> <td>Harmful if inhaled </td> <td>Acute toxicity,<br>inhalation </td> <td>Category 4 </td> <td>Warning</td> <td>P261, P271, P304+P340, P312</td> <tr> <td>H333</td> <td>May be harmful if inhaled </td> <td>Acute toxicity,<br>inhalation </td> <td>Category 5 </td> <td></td> <td>P304+P312</td> <tr> <td>H334</td> <td>May cause allergy<br> or asthma symptoms <br>or breathing difficulties if inhaled </td> <td>Sensitisation, <br>respiratory </td> <td>Category 1 </td> <td>Danger</td> <td>P261, P285, P304+P341, P342+P311, P501</td> <tr> <td>H335</td> <td>May cause respiratory irritation </td> <td>Specific target organ toxicity, <br>single exposure; <br>Respiratory <br>tract irritation</td> <td>Category 3 </td> <td>Warning</td> <td></td> <tr> <td>H336</td> <td>May cause drowsiness <br>or dizziness </td> <td>Specific target organ toxicity,<br>single exposure; <br>Narcotic effects</td> <td>Category 3 </td> <td>Warning</td> <td>P261, P271, P304+P340, P312, P403+P233, P405, P501 </td> <tr> <td>H340</td> <td>May cause genetic defects </td> <td>Germ cell mutagenicity </td> <td>Category 1A, 1B </td> <td>Danger</td> <td></td> <tr> <td>H341</td> <td>Suspected of causing genetic defects </td> <td>Germ cell mutagenicity </td> <td>Category 2 </td> <td>Warning</td> <td>P201,P202, P281, P308+P313, P405, P501</td> <tr> <td>H350</td> <td>May cause cancer </td> <td>Carcinogenicity</td> <td>Category 1A, 1B </td> <td>Danger</td> <td></td> <tr> <td>H351</td> <td>Suspected of causing cancer </td> <td>Carcinogenicity</td> <td>Category 2 </td> <td>Warning</td> <td>P201, P202, P281, P308+P313, P405, P501</td> <tr> <td>H360</td> <td>May damage fertility <br>or the unborn child </td> <td>Reproductive toxicity </td> <td>Category 1A, 1B </td> <td>Danger</td> <td></td> <tr> <td>H361</td> <td>Suspected of damaging fertility <br>or the unborn child </td> <td>Reproductive toxicity </td> <td>Category 2 </td> <td>Warning</td> <td>P201, P202, P281, P308+P313, P405, P501</td> <tr> <td>H362</td> <td>May cause harm to breast-fed children </td> <td>Reproductive toxicity, <br>effects on or via lactation</td> <td>Additional category </td> <td></td> <td>P201, P260, P263, P264, P270, P308+P313</td> <tr> <td>H370</td> <td>Causes damage to organs </td> <td>Specific target organ toxicity, <br>single exposure </td> <td>Category 1 </td> <td>Danger</td> <td>P260, P264, P270, P307+P311, P321, P405, P501</td> <tr> <td>H371</td> <td>May cause damage to organs </td> <td>Specific target organ toxicity, <br>single exposure </td> <td>Category 2</td> <td>Warning</td> <td>P260, P264, P270, P309+P311, P405, P501</td> <tr> <td>H372</td> <td>Causes damage to organs through prolonged <br>or repeated exposure </td> <td>Specific target organ toxicity, <br>repeated exposure </td> <td>Category 1 </td> <td>Danger</td> <td>P260, P264, P270, P314, P501</td> <tr> <td>H373</td> <td>May cause damage to organs <br>through prolonged <br>or repeated exposure </td> <td>Specific target organ toxicity, <br>repeated exposure </td> <td>Category 2 </td> <td>Warning</td> <td>P260, P314, P501</td> <tr> <td>H400</td> <td>Very toxic to aquatic life </td> <td>Hazardous to the aquatic environment, <br>acute hazard</td> <td>Category 1 </td> <td>Warning</td> <td>P273, P391, P501</td> <tr> <td>H401</td> <td>Toxic to aquatic life </td> <td>Hazardous to the aquatic environment, <br>acute hazard</td> <td>Category 2 </td> <td></td> <td>P273, P501</td> <tr> <td>H402</td> <td>Harmful to aquatic life </td> <td>Hazardous to the aquatic environment, <br>acute hazard</td> <td>Category 3 </td> <td></td> <td></td> <tr> <td>H410</td> <td>Very toxic to aquatic life <br>with long lasting effects </td> <td>Hazardous to the aquatic environment, <br>long-term hazard</td> <td>Category 1 </td> <td>Warning</td> <td>P273, P391, P501</td> <tr> <td>H411</td> <td>Toxic to aquatic life <br>with long lasting effects </td> <td>Hazardous to the aquatic environment, <br>long-term hazard</td> <td>Category 2 </td> <td></td> <td></td> <tr> <td>H412</td> <td>Harmful to aquatic life <br>with long lasting effects </td> <td>Hazardous to the aquatic environment, <br>long-term hazard</td> <td>Category 3 </td> <td></td> <td></td> <tr> <td>H413</td> <td>May cause long lasting <br>harmful effects to aquatic life </td> <td>Hazardous to the aquatic environment, <br>long-term hazard</td> <td>Category 4 </td> <td></td> <td>P273, P501</td> <tr> <td>H420</td> <td>Harms public health and <br>the environment by destroying ozone in the upper atmosphere</td> <td>Hazardous to the ozone layer </td> <td>Category 1 </td> <td>Warning</td> <td>P502</td> <tr> <td colspan="6">Additional Hazard statements - EU Left-overs </td> <tr> <td>EUH001</td> <td colspan="5">Explosive when dry</td> <tr> <td>EUH006</td> <td colspan="5">Explosive with or without contact with air</td> <tr> <td>EUH014</td> <td colspan="5">Reacts violently with water</td> <tr> <td>EUH018</td> <td colspan="5">In use may form flammable/explosive vapour-air mixture</td> <tr> <td>EUH019</td> <td colspan="5">May form explosive peroxides</td> <tr> <td>EUH029</td> <td colspan="5">Contact with water liberates toxic gas</td> <tr> <td>EUH031</td> <td colspan="5">Contact with acids liberates toxic gas</td> <tr> <td>EUH032</td> <td colspan="5">Contact with acids liberates very toxic gas</td> <tr> <td>EUH044</td> <td colspan="5">Risk of explosion if heated under confinement</td> <tr> <td>EUH059</td> <td colspan="5">Hazardous to the ozone layer</td> <tr> <td>EUH066</td> <td colspan="5">Repeated exposure may cause skin dryness or cracking</td> <tr> <td>EUH070</td> <td colspan="5">Toxic by eye contact</td> </tr> </div> </html> </table> <script> var coll = document.getElementsByClassName("collapsible"); var i; for (i = 0; i < coll.length; i++) { coll[i].addEventListener("click", function() { this.classList.toggle("active"); var content = this.nextElementSibling; if (content.style.maxHeight){ content.style.maxHeight = null; } else { content.style.maxHeight = content.scrollHeight + "px"; } }); } </script> </table> </content> </div class="content"> <!DOCTYPE html> <html> <body2> <p> <div class=" aem-GridColumn aem-GridColumn--default--9"><div class="MuiTypography-root aem-ms-text-cmp jss185 MuiTypography-body2"><h2><a id="precautionary"></a>PRECAUTIONARY STATEMENTS</h2> <p><b>There are 116 individual and 33 combined Precautionary statements </b> – these are assigned a unique alphanumerical code which consists of one letter and three numbers as follows:</p> <ul> <li>the letter &quot;P&quot; (for &quot;precautionary statement&quot;);</li> <li>one number designating the type of precautionary statement as follows: <ul> <li>&quot;1&quot; for general precautionary statements</li> <li>&quot;3&quot; for response precautionary statements</li> <li>&quot;4&quot; for storage precautionary statements</li> <li>&quot;5&quot; for disposal precautionary statements</li> </ul> </li> <li>two numbers (corresponding to the sequential numbering of precautionary statements) </li> </ul> <br> <style> .button3 { border: 3px solid #007CBA ; border-radius: 10px; color: white; padding: 10px 20px; text-align: center; text-decoration: none; font-size: 18px; margin: 3px 0px; cursor: pointer; } .button3 {background-color: #007CBA;} </style> <a target="_blank" href="https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/312/993/p_overview.pdf" class="button button3"> <font color="white"><strong>Precautionary Statement Overview</strong></font> </a> </button> <ul> <br> <!DOCTYPE html> <html> <head> <meta name="viewport" content2="width=device-width, initial-scale=1"> <style> .collapsible1 { background-color: #f1f1f1; color: black; cursor: pointer; padding: 18px; width: 100%; border: none; text-align: left; font-size: 18px; } .content2 { padding: 0 30px; max-height: 0; overflow: hidden; background-color: #f1f1f1; word-wrap: break-word; column-gap: 50px;} </style> </head> <body> <button class="collapsible1"></i> &#x25BC <b>PRECAUTIONARY STATEMENTS CHART</b></button> <div class="content2"> <style> th,td,tr { border-bottom: solid; border-bottom-color: #b6b7b8; border-bottom-width: 1px;} th{ background-color: #FFFFFF; } th, td{ word-wrap: break-word; } th, td { padding-top: 40px; padding-bottom: 40px; padding-left: 50px; padding-right: 50px; column-gap: 70px; } table { border-spacing: 00px; } th, td { text-align: left;} Td,th { font-size: 95%; } td { font-weight: normal; } table,th,td { column-gap: 50px; } </style> <table style="width:100%"> <tr> <th colspan="6">General</th> <tr> <td>P101</td> <td colspan="5">If medical advice is needed,have product container or label at hand.</td> <tr> <tr> <td>P102</td> <td colspan="5">Keep out of reach of children.</td> <tr> <td>P103</td> <td colspan="5">Read label before use</td> <tr> <th colspan="5">Prevention</th> <tr> <td>P201</td> <td colspan="5">Obtain special instructions before use.</td> <tr> <td>P202</td> <td colspan="5">Do not handle until all safety precautions have been read and understood.</td> <tr> <td>P210</td> <td colspan="5">Keep away from heat/sparks/open flames/hot surfaces. — No smoking.</td> <tr> <td>P211</td> <td colspan="5">Do not spray on an open flame or other ignition source.</td> <tr> <td>P220</td> <td colspan="5">Keep/Store away from clothing/…/combustible materials.</td> <tr> <td>P221</td> <td colspan="5">Take any precaution to avoid mixing with combustibles/…</td> <tr> <td>P222</td> <td colspan="5">Do not allow contact with air.</td> <tr> <td>P223</td> <td colspan="5">Keep away from any possible contact with water, because of violent reaction and possible flash fire.</td> <tr> <td>P230</td> <td colspan="5">Keep wetted with …</td> <tr> <td>P231</td> <td colspan="5">Keep wetted with …</td> <tr> <td>P232</td> <td colspan="5">Protect from moisture.</td> <tr> <td>P233</td> <td colspan="5">Keep container tightly closed.</td> <tr> <td>P234</td> <td colspan="5">Keep only in original container.</td> <tr> <td>P235</td> <td colspan="5">Keep cool.</td> <tr> <td>P240</td> <td colspan="5">Ground/bond container and receiving equipment.</td> <tr> <td>P241</td> <td colspan="5">Use explosion-proof electrical/ventilating/lighting/…/equipment.</td> <tr> <td>P242</td> <td colspan="5">Use only non-sparking tools.</td> <tr> <td>P243</td> <td colspan="5">Take precautionary measures against static discharge.</td> <tr> <td>P244</td> <td colspan="5">Keep reduction valves free from grease and oil.</td> <tr> <td>P250</td> <td colspan="5">Do not subject to grinding/shock/…/friction.</td> <tr> <td>P251</td> <td colspan="5">Pressurized container: Do not pierce or burn, even after use.</td> <tr> <td>P260</td> <td colspan="5">Do not breathe dust/fume/gas/mist/vapours/spray.</td> <tr> <td>P261</td> <td colspan="5">Avoid breathing dust/fume/gas/mist/vapours/spray.</td> <tr> <td>P262</td> <td colspan="5">Do not get in eyes, on skin, or on clothing.</td> <tr> <td>P263</td> <td colspan="5">Avoid contact during pregnancy/while nursing.</td> <tr> <td>P264</td> <td colspan="5">Wash hands thoroughly after handling.</td> <tr> <td>P270</td> <td colspan="5">Do not eat, drink or smoke when using this product.</td> <tr> <td>P271</td> <td colspan="5">Use only outdoors or in a well-ventilated area.</td> <tr> <td>P272</td> <td colspan="5">Contaminated work clothing should not be allowed out of the workplace.</td> <tr> <td>P273</td> <td colspan="5">Avoid release to the environment.</td> <tr> <td>P280</td> <td colspan="5">Wear protective gloves/protective clothing/eye protection/face protection.</td> <tr> <td>P281</td> <td colspan="5">Use personal protective equipment as required.</td> <tr> <td>P282</td> <td colspan="5">Wear cold insulating gloves/face shield/eye protection.</td> <tr> <td>P283</td> <td colspan="5">Wear fire/flame resistant/retardant clothing.</td> <tr> <td>P284</td> <td colspan="5">Wear respiratory protection.</td> <tr> <td>P285</td> <td colspan="5">In case of inadequate ventilation wear respiratory protection.</td> <tr> <td>P231 + P232 </td> <td colspan="5">Handle under inert gas. Protect from moisture.</td> <tr> <td>P235 + P410 </td> <td colspan="5">Keep cool. Protect from sunlight.</td> <tr> <th colspan="6">Response</th> <tr> <td>P301</td> <td colspan="5">IF SWALLOWED:</td> <tr> <td>P304</td> <td colspan="5">IF INHALED:</td> <tr> <td>P305</td> <td colspan="5">IF IN EYES:</td> <tr> <td>P306</td> <td colspan="5">IF ON CLOTHING:</td> <tr> <td>P307</td> <td colspan="5">IF exposed:</td> <tr> <td>P308</td> <td colspan="5">IF exposed or concerned:</td> <tr> <td>P309</td> <td colspan="5">IF exposed or if you feel unwell:</td> <tr> <td>P310</td> <td colspan="5">Immediately call a POISON CENTER or doctor/physician.</td> <tr> <td>P311</td> <td colspan="5">Call a POISON CENTER or doctor/physician.</td> <tr> <td>P312</td> <td colspan="5">Call a POISON CENTER or doctor/physician if you feel unwell.</td> <tr> <td>P313</td> <td colspan="5">Get medical advice/attention.</td> <tr> <td>P314</td> <td colspan="5">Get medical advice/attention if you feel unwell.</td> <tr> <td>P315</td> <td colspan="5">Get immediate medical advice/attention.</td> <tr> <td>P320</td> <td colspan="5">Specific treatment is urgent (see … on this label).</td> <tr> <td>P321</td> <td colspan="5">Specific treatment (see … on this label).</td> <tr> <td>P322</td> <td colspan="5">Specific measures (see …on this label).</td> <tr> <td>P330</td> <td colspan="5">Rinse mouth.</td> <tr> <td>P331</td> <td colspan="5">Do NOT induce vomiting.</td> <tr> <td>P332</td> <td colspan="5">IF SKIN irritation occurs:</td> <tr> <td>P333</td> <td colspan="5">If skin irritation or rash occurs:</td> <tr> <td>P334</td> <td colspan="5">Immerse in cool water/wrap n wet bandages.</td> <tr> <td>P335</td> <td colspan="5">Brush off loose particles from skin.</td> <tr> <td>P336</td> <td colspan="5">Thaw frosted parts with lukewarm water. Do not rub affected area.</td> <tr> <td>P337</td> <td colspan="5">If eye irritation persists:</td> <tr> <td>P338</td> <td colspan="5">Remove contact lenses, if present and easy to do. Continue rinsing.</td> <tr> <td>P340</td> <td colspan="5">Remove victim to fresh air and keep at rest in a position comfortable for breathing.</td> <tr> <td>P341</td> <td colspan="5">If breathing is difficult, remove victim to fresh air and keep at rest in a position </td> <tr> <td>P342</td> <td colspan="5">If experiencing respiratory symptoms:</td> <tr> <td>P350</td> <td colspan="5">Gently wash with plenty of soap and water.</td> <tr> <td>P351</td> <td colspan="5">Rinse cautiously with water for several minutes.</td> <tr> <td>P352</td> <td colspan="5">Wash with plenty of soap and water.</td> <tr> <td>P353</td> <td colspan="5">Rinse skin with water/shower.</td> <tr> <td>P360</td> <td colspan="5">Rinse immediately contaminated clothing and skin with plenty of water before removin</td> <tr> <td>P361</td> <td colspan="5">Remove/Take off immediately all contaminated clothing.</td> <tr> <td>P362</td> <td colspan="5">Take off contaminated clothing and wash before reuse.</td> <tr> <td>P363</td> <td colspan="5">Wash contaminated clothing before reuse.</td> <tr> <td>P370</td> <td colspan="5">In case of fire:</td> <tr> <td>P371</td> <td colspan="5">In case of major fire and large quantities:</td> <tr> <td>P372</td> <td colspan="5">Explosion risk in case of fire.</td> <tr> <td>P373</td> <td colspan="5">DO NOT fight fire when fire reaches explosives.</td> <tr> <td>P374</td> <td colspan="5">Fight fire with normal precautions from a reasonable distance.</td> <tr> <td>P376</td> <td colspan="5">Stop leak if safe to do so. Oxidising gases (section 2.4) 1</td> <tr> <td>P377</td> <td colspan="5">Leaking gas fire: Do not extinguish, unless leak can be stopped safely.</td> <tr> <td>P378</td> <td colspan="5">Use … for extinction.</td> <tr> <td>P380</td> <td colspan="5">Evacuate area.</td> <tr> <td>P381</td> <td colspan="5">Eliminate all ignition sources if safe to do so.</td> <tr> <td>P390</td> <td colspan="5">Absorb spillage to prevent material damage.</td> <tr> <td>P391</td> <td colspan="5">Collect spillage. Hazardous to the aquatic environment.</td> <tr> <td>P301 + P310 </td> <td colspan="5">IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.</td> <tr> <td>P301 + P312 </td> <td colspan="5">IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.</td> <tr> <td>P301 + P330 + P331 </td> <td colspan="5">IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.</td> <tr> <td>P302 + P350 </td> <td colspan="5">IF ON SKIN: Gently wash with plenty of soap and water.</td> <tr> <td>P302 + P352 </td> <td colspan="5">IF ON SKIN: wash with plenty of soap and water.</td> <tr> <td>P303 + P361 + P353 </td> <td colspan="5">IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.</td> <tr> <td>P304 + P312 </td> <td colspan="5">IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.</td> <tr> <td>P304 + P340 </td> <td colspan="5">IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. </td> <tr> <td>P304 + P341 </td> <td colspan="5">IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. </td> <tr> <td>P305 + P351 + P338 </td> <td colspan="5">IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. </td> <tr> <td>P306 + P360 </td> <td colspan="5">IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. </td> <tr> <td>P307 + P311 </td> <td colspan="5">IF exposed: call a POISON CENTER or doctor/physician. </td> <tr> <td>P308 + P313 </td> <td colspan="5">IF exposed or concerned: Get medical advice/attention. </td> <tr> <td>P309 + P311</td> <td colspan="5">IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. </td> <tr> <td>P332 + P313 </td> <td colspan="5">IF SKIN irritation occurs: Get medical advice/attention. </td> <tr> <td>P333 + P313 </td> <td colspan="5">IF SKIN irritation or rash occurs: Get medical advice/attention. </td> <tr> <td>P335 + P334 </td> <td colspan="5">Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. </td> <tr> <td>P337 + P313 </td> <td colspan="5">IF eye irritation persists: Get medical advice/attention. </td> <tr> <td>P342 + P311 </td> <td colspan="5">IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. </td> <tr> <td>P370 + P376 </td> <td colspan="5">in case of fire: Stop leak if safe to Do so. </td> <tr> <td>P370 + P378 </td> <td colspan="5">In case of fire: Use … for extinction. </td> <tr> <td>P370 + P380 </td> <td colspan="5">in case of fire: Evacuate area. </td> <tr> <td>P370 + P380 + P375 </td> <td colspan="5">in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. </td> <tr> <td>P371 + P380 + P375 </td> <td colspan="5">in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. </td> </tr> </div> <script> var coll = document.getElementsByClassName("collapsible1"); var i; for (i = 0; i < coll.length; i++) { coll[i].addEventListener("click", function() { this.classList.toggle("active"); var content = this.nextElementSibling; if (content.style.maxHeight){ content.style.maxHeight = null; } else { content.style.maxHeight = content.scrollHeight + "2px"; } }); } </script> </table> </content> </div class="content"> <!DOCTYPE html> <html> <body3> <p> <div class=" aem-GridColumn aem-GridColumn--default--9"><div class="MuiTypography-root aem-ms-text-cmp jss185 MuiTypography-body2"><h2><a id="pictogram"></a>PICTOGRAMS AND HAZARD CODES</h2> <p>Compared to the current EU system the most noticeable change are the pictograms (formerly: hazard symbols). While the most of the GHS pictograms have an equivalent in the old system, the pictograms GHS 04, GHS 07 and GHS 08 are completely new.</p> <p>The GHS System is built on 16 physical, 10 health and 3 environmental hazard classes and comprises the following communication elements:</p> <br> <!DOCTYPE html> <html> <head> <meta name="viewport" content3="width=device-width, initial-scale=1"> <style> .collapsible2 { background-color: #f1f1f1; color: black; cursor: pointer; padding: 18px; width: 100%; border: none; text-align: left; font-size: 18px; } .content3 { padding: 0 30px; max-height: 0; overflow: hidden; background-color: #f1f1f1; word-wrap: break-word; column-gap: 50px; } </style> <body> <button class="collapsible2"></i> &#x25BC <b>9 PICTOGRAMS CHART</b></button> <div class="content3"> <div class="MuiCollapse-wrapperInner"> <style> th,td,tr { border-bottom: solid; border-bottom-color: #b6b7b8; border-bottom-width: 1px;} th{ background-color: #FFFFFF; } th, td{ word-wrap: break-word; column-gap: 70px; } th, td { padding-top: 40px; padding-bottom: 40px; padding-left: 50px; padding-right: 50px; column-gap: 50px; } .paddingBetweenCols td { padding: 0 25px; } table { border-spacing: 00px; } th, td { text-align: left;} Td,th { font-size: 95%; } td { font-weight: normal; } le,th,td { column-gap: 60px; } </style> <table style="width:100%"> <tr class="MuiTableRow-root"> <th style="width:25%">Description</th> <th style="width:20%">Pictogram</th> <dd><th style="width:55%" colspan="4">Hazard class and hazard category:</th><dd> </tr> <tr> <td>Exploding Bomb GHS01</td> <td><img src="{{media url=wysiwyg/exploding-bomb-pictogram.jpg}}" alt="Exploding Bomb GHS01 " style="width:100px;height:100px;" /></img></td> <td> Unstable explosives <br> Explosives of Divisions 1.1, 1.2, 1.3, 1.4 <br> Self reactive substances and mixtures, Types A,B <br> Organic peroxides, Types A,B <br> Fire or projection hazard Division 1.5 <br> May mass explode in fire Division 1.6</td> <tr> <td>Flame GHS02</td> <td><img src="{{media url=wysiwyg/flame-pictogram.jpg}}" alt="Flame GHS02 " style="width:100px;height:100px;" /></td> <td colspan="4">Flammable gases, category 1 <br> Flammable aerosols, categories 1,2 <br> Flammable liquids, categories 1,2,3 <br> Flammable solids, categories 1,2 <br> Self-reactive substances and mixtures, Types B,C,D,E,F <br> Pyrophoric liquids, category 1 <br> Pyrophoric solids, category 1 <br> Self-heating substances and mixtures, categories 1,2 <br> Substances and mixtures, which in contact with water, <br> emit flammable gases, categories 1,2,3 <br> Organic peroxides, Types B,C,D,E,F</td> <tr> <td>Flame Over Circle GHS03</td> <td><img src="{{media url=wysiwyg/flame-over-circle-pictogram.jpg}}" alt="Flame Over Circle GHS03" style="width:100px;height:100px;" /></td> <td colspan="4">Oxidizing gases, category 1 Oxidizing liquids, categories 1,2,3</td> <tr> <td>Gas Cylinder GHS04</td> <td><img src="{{media url=wysiwyg/gas-cylinder-pictogram.jpg}}" alt="Gas Cylinder GHS04" style="width:100px;height:100px;" /></td> <td colspan="4">Gases under pressure: <br> Compressed gases <br> Liquefied gases <br> Refrigerated liquefied gases <br> Dissolved gases</td> <tr> <td>Corrosion GHS05</td> <td><img src="{{media url=wysiwyg/corrosion-pictogram.jpg}}" alt="Corrosion GHS05" style="width:100px;height:100px;" /></td> <td colspan="4">Corrosive to metals, category 1 <br> Skin corrosion, categories 1A,1B,1C <br> Serious eye damage, category 1 </td> <tr> <td>Skull and Crossbones GHS06</td> <td><img src="{{media url=wysiwyg/skull-pictogram.jpg}}" alt="Skull and Crossbones GHS06" style="width:100px;height:100px;" /></td> <td colspan="4">Acute toxicity (oral, dermal, inhalation), categories 1,2,3 </td> <tr> <td>Exclamation Mark GHS07</td> <td><img src="{{media url=wysiwyg/exclamation-mark-pictogram.jpg}}" alt="Exclamation Mark GHS07" style="width:100px;height:100px;" /></td> <td colspan="4">Acute toxicity (oral, dermal, inhalation), category 4 <br> Skin irritation, category 2 <br> Eye irritation, category 2 <br> Skin sensitisation, category 1 <br> Specific Target Organ Toxicity – Single exposure, category 3 </td> <tr> <td>Health Hazard GHS08</td> <td><img src="{{media url=wysiwyg/health-hazard-pictogram.jpg}}" alt="Health Hazard GHS08" style="width:100px;height:100px;" /></td> <td colspan="4">Respiratory sensitization, category 1 <br> Germ cell mutagenicity, categories 1A,1B,2 <br> Carcinogenicity, categories 1A,1B,2 <br> Reproductive toxicity, categories 1A,1B,2 <br> Specific Target Organ Toxicity – Single exposure, categories 1,2 <br> Specific Target Organ Toxicity – Repeated exposure, categories 1,2 <br> Aspiration Hazard, category 1 </td> <tr> <td>Environment GHS09</td> <td><img width="100%" height="100%" src="{{media url=wysiwyg/environment-pictogram.jpg}}" alt="Environment GHS09" style="width:100px;height:100px;" /></td> <td colspan="4">Hazardous to the aquatic environment <br> - Acute hazard, category1 <br> - Chronic hazard, categories 1,2 </td> <tr> </td> </tr> </div> <script> var coll = document.getElementsByClassName("collapsible2"); var i; for (i = 0; i < coll.length; i++) { coll[i].addEventListener("click", function() { this.classList.toggle("active"); var content = this.nextElementSibling; if (content.style.maxHeight){ content.style.maxHeight = null; } else { content.style.maxHeight = content.scrollHeight + "2px"; } }); } </script> </table> </content3> </body> </html>